The same result can be achieved by setting the connection limit for that user to 0:
pguser=# alter user bob connection limit 0;ALTER ROLE
To allow 10 concurrent connections for the bob user, run this command:
pguser=# alter user bob connection limit 10;ALTER ROLE
To allow an unlimited number of connections for this user, run the following:
pguser=# alter user bob connection limit -1;ALTER ROLE